Please check the pin assignment in PSoC Creator and schematic of the CY4532.
CY4532 do not have this function.
i will rephrase the question
HW : CY4532 EZ-PD CCG3PA EVL ( MAIN+POWER borads) - link https://www.cypress.com/documentation/development-kitsboards/cy4532-ez-pd-ccg3pa-evaluation-kit
FW : .EZ-PD CCGx Power Software Development Kit - link https://www.cypress.com/documentation/software-and-drivers/ez-pd-ccgx-power-software-development-kit
the sdk have project example i choose C:\Program Files (x86)\Cypress\EZ-PD CCGx Power SDK\CCGx\Firmware\projects\CYPD3171-24LQXQ_pb\CYPD3171-24LQXQ_pb.cydsn project
config.h include define #define APP_FW_LED_ENABLE
main.c the function led_timer_cb toggle FW_LED_GPIO_PORT_PIN
in the image you see that GPIO_PORT_2_PIN_0 define as DIR_CTRL_C
in scheme of main and power board the only LED is LED1 which jumper J14 control
so what is the meaning of this option APP_FW_LED_ENABLE in config.h file ?
APP_FW_LED_ENABLE is a marco for blinking LED to indicate whether the firmware is running.
As you can see, APP_FW_LED_ENABLE is not enabled in the firmware by default. You should have a customed board which use a GPIO to drive a LED to use this function. Then you can enable APP_FW_LED_ENABLE and set FW_LED_GPIO_PORT_PIN to the correct pin. As I have said, CY4532 do not have this feature.