Can you please also share the CC logs?
Not sure if our case is different but we are using the CY4532 EVK with (Cypress default) PA firmware and SINK is CY4533 EVK. Modified the PDOs to support up to 20V. Interconnect cable is the E-marked USB 3.1 Gen2 cable (Digikey p/n Q1243-ND).
Each contract is being selected correctly using this Qualtek cable and rotating the rotary switch on the CY4533.