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As you already know that this kit is solar powered and the BLE devices gets power through PMIC which basically supports two modes as described at page # 9 of CYALKIT-E02 User guide (https://www.cypress.com/file/280601/download ) -
1) Demo mode, transmitting sensor data at 3- to 60-second intervals (without charging to a supercapacitor)
2) Timer mode, transmitting sensor data at 5-minute intervals while charging to the supercapacitor
So, using the solar power , it will be difficult to advertise at 100ms. You can also have a look down to the user guide for charging ,discharging profile of PMIC.